Spells
Petrificus Totalus
Petrificus Totalus is the Full Body-Bind. The victim’s arms and legs snap together and they fall, rigid and awake. Hermione casts it on Neville when he tries to stop the trio leaving the common room to protect the Philosopher’s Stone. Draco uses it on Harry on the Hogwarts Express in the sixth year.

First mention
Harry Potter and the Philosopher's StoneChapter: Through the Trapdoor
Neville is left bound on the common-room floor as Harry, Ron, and Hermione leave for the trapdoor.